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Organic Semiconductor Materials & OLED Polymer

Poly(triarylamine) Derivatives

Poly[bis(4-phenyl)(2,4-dimethylphenyl)amine

CAS: Unknown
Chemical Formula: (C20H17N)n
Storage: Store in a cool, dark place
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Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine

CAS: 1333317-99-9
Chemical Formula: (C21H19N)n
Storage: Store in a cool, dark place
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Poly[bis(4-phenyl)
(3-methoxyphenyl)amineCA

CAS: Unknown
Chemical Formula: (C19H15NO)n
Storage: Store in a cool, dark place
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Poly[bis(4-phenyl)
(4-fluorophenyl)amine

CAS: Unknow
Chemical Formula: (C18H12NF)n
Storage: Store in a cool, dark place
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Poly[bis(4-phenyl)
(2,4-difluorophenyl)amine

CAS: Unknown
Chemical Formula: (C18H11NF2)n
Storage: Store in a cool, dark place
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Poly[bis(4-phenyl)
(pentafluorophenyl)amine

CAS: Unknow
Chemical Formula: (C18H8NF5)n
Storage: Store in a cool, dark place
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Polytriarylamines are a class of air-stable organic semiconductors, which are a result of the low-lying HOMO energy limiting air oxidation. Long-term operation of these materials is further validated by their inertness to fluctuations in current due to changes in humidity, with charge mobilities of up to 5×10-3 cm2/Vs being observed.
Their excellent solubility in organic solvents, beyond the conventional chlorinated aromatics, means that they can be easily processed into devices. Average molecular weights can be tuned for specific applications, and we encourage requests for specific ranges.

Pentacene Derivatives

6,13-bis(triethylsilyl)ethynylpentacene
(TES Pentacene)

CAS: 398128-81-9
Chemical Formula: C38H42Si2
Molecular Weight: 554.91
Storage:
Store in a cool, dark place
Recommended Solvents: Anisole, butyl Benzene, chlorobenzene, chloroform, dichlorobenzene, tetrahydrofuran, toluene, xylene.
Purity: 99.5% (typically >99.9%) by HPLC
Appearance: Dark Blue Solid
Melting Point: 261-266 °C
TES-Pentacene can be used as a p-type semiconductor and also as an additive when combined with other semiconducting materials for use in Organic Photovoltaic Devices. It has excellent solubility in organic solvents allowing it to be easily processed into devices. Due to restrictions, we can only supply this material to countries outside of the USA.
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1,4,8,10-tetramethyl-6,13-bis(triethylsilyl)ethynylpentacene
(TMTES Pentacene)

CAS: 1173698-76-4
Chemical Formula: C42H50Si2
Molecular Weight: 611.02
Storage:
Store in a cool, dark place
Recommended Solvents: Anisole, butyl Benzene, chlorobenzene, chloroform, dichlorobenzene, tetrahydrofuran, toluene, xylene.
Purity: 99.5% (typically >99.9%) by HPLC
Appearance: Dark Blue Solid
Melting Point: 257-259 °C
TMTES Pentacene is a soluble derivative of pentacene which has applications as a semiconductor for both device fabrication and the investigation of charge transport of solution-processed crystal semiconductors. Mobilities of up to 4.34 cm2/Vs have been measured within the literature. Due to restrictions, we can only supply this material to countries outside of the USA.
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6,13-bis(triisopropylsilyl)ethynylpentacene
(TIPS Pentacene)

CAS: 373596-08-8
Chemical Formula: C44H54Si2
Molecular Weight: 639.07
Storage:
Store in a cool, dark place
Recommended Solvents: Anisole, butyl Benzene, chlorobenzene, chloroform, dichlorobenzene, tetrahydrofuran, toluene, xylene.
Purity: 99.5% (typically >99.9%) by HPLC
Appearance: Dark Blue Solid
Melting Point: 259 °C
TES-Pentacene can be used as a p-type semiconductor and also as an additive when combined with other semiconducting materials for use in Organic Photovoltaic Devices. It has excellent solubility in organic solvents allowing it to be easily processed into devices. Due to restrictions, we can only supply this material to countries outside of the USA.
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Poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT)

CAS: 210347-52-7
Chemical Formula: (C35H42N2S)n
Molecular Weight Average (Mn): Numerous
Storage:
Store in a cool, dark place
Recommended Solvents: Anisole, butyl Benzene, chlorobenzene, chloroform, dichlorobenzene, tetrahydrofuran, toluene, xylene.
Purity: 99.9%
Appearance: Orange Powder
Solubility: THF, Chloroform
F8BT is a widely used green emitting fluorene copolymer (λem=529 nm in THF solutions), typically used in a variety of applications such as an emitting species in OLEDs, as a polymeric acceptor in photovoltaic cells or within transistor applications. The low-lying energies of the HOMO and LUMO make this species particularly air stable.
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Molecular Imaging Intermediates

Optical Imaging Intermediates

5-carboxyfluorescein diacetate NHS ester

CAS: 150206-05-6
Chemical Formula: C29H19NO11
Molecular Weight: 557.46
λex= 492nm, λem=517nm
Storage: = -20°C in darkness
HPLC Purity: = ≥90%
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6-carboxyfluorescein diacetate NHS ester

CAS: 150206-15-8
Chemical Formula: C29H19NO11
Molecular Weight: 557.46
λex= 492nm, λem=517nm
Storage: = -20°C in darkness
HPLC Purity: = ≥90%
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Regioisomerically pure carboxyfluorescein diacetate NHS esters are capable of rapid and irreversible labelling of amine reactive sites. Additional cell permeability arises from the presence of the acetate ester functionality which is hydrolysed by esterase enzymes once within the cell, allowing the fluorescent dye to accumulate within cells.

Tetramethylrhodamine 5-NHS ester

CAS: 150810-68-7
Chemical Formula: C29H25N3O7
Molecular Weight: 527.52
λex= 543nm, λem=578nm
Storage: = -20°C in darkness
HPLC Purity: = ≥90%
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Tetramethylrhodamine 6-NHS ester

CAS: 150810-69-8
Chemical Formula: C29H25N3O7
Molecular Weight: 527.52
λex= 543nm, λem=575nm
Storage: = -20°C in darkness
HPLC Purity: = ≥90%
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Regioisomerically pure tetremethylrhodamine NHS esters are capable of rapid and irreversible labelling of amine reactive sites, typically for protein labelling. Emission is red-shifted with respect to the fluorescein analogues.

Reactive Chelator

Tritertbutyl-1,4,7,10-tetrazacyclododecane-1,4,7-triacetate (DO3A tBu)

CAS: 122555-91-3
Chemical Formula: C26H50N4O6
Molecular Weight: 514.70
Storage: -20°C (hygroscopic at RT)
Chemical Purity: = ≥95% (NMR Spectroscopy)
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1,4,7-Triboc-1,4,7,10-tetrazacyclododecane (TriBoc Cyclen)

CAS: 175854-39-4
Chemical Formula: C23H44N4O6
Molecular Weight: 472.62
Storage: 2-8°C (hygroscopic at RT)
Chemical Purity: = ≥95% (NMR Spectroscopy)
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1,4,7,10-tetrazacyclododecane-1,7-bis(tertbutyl)acetate (DO2A tBu)

CAS: 162148-48-3
Chemical Formula: C20H40N4O4
Molecular Weight: 400.6
Storage: -20°C (hygroscopic at RT)
Chemical Purity: = ≥95% (NMR Spectroscopy)
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1,4,7,10-tetrazacyclododecane-1,7-bis(benzylcarbamide) (DiCBz)

CAS: 162148-45-0
Chemical Formula: C24H32N4O4
Molecular Weight: 440.5
Storage: -20°C (hygroscopic at RT)
Chemical Purity: = ≥95% (NMR Spectroscopy)
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1,4,7-triazacyclononane-3-N-Boc-Lysine

CAS: Unknown
Chemical Formula: C15H32N4O2
Molecular Weight: 300.25
Storage: -20°C (hygroscopic at RT)
Chemical Purity: = ≥95% (NMR Spectroscopy)
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Macrocyclic metal chelators have been utilised throughout the biochemical industry for numerous years. These specific examples act as reactive intermediates which can be labelled with targeting vectors prior to deprotection and complexation with an appropriate metal centre. Typically, metals such as gadolinium, copper or zinc have been used to generate targeted MRI contrast agents, radiopharmaceuticals or phosphate anion receptors, respectively.

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